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Quantum photoelectrochemistry : ウィキペディア英語版
Quantum photoelectrochemistry
Quantum photoelectrochemistry is the investigation of the quantum mechanical nature and associated aspects of photoelectrochemistry, the subfield of study within physical chemistry concerned with the interaction of light with electrochemical systems, through the application of quantum chemical calculations.〔Quantum Photoelectrochemistry - Theoretical Studies of Organic Adsorbates on Metal Oxide Surfaces, Petter Persson, Acta Univ. Upsaliensis., Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 544, 53 pp. Uppsala. ISBN 91-554-4736-8.〕 Quantum photoelectrochemistry provides an expansion of quantum electrochemistry to processes involving also the interaction with light (photons). It therefore also includes essential elements of photochemistry. Key aspects of quantum photoelectrochemistry are calculations of optical excitations, photoinduced electron and energy transfer processes, excited state evolution, as well as interfacial charge separation and charge transport in nanoscale energy conversion systems.〔Multiscale Modelling of Interfacial Electron Transfer, Petter Persson, Chapter 3 in: Solar Energy Conversion – Dynamics of Electron and Excitation Transfer P. Piotrowiak (Ed.), RSC Energy and Environment Series (2013)〕
Important and emerging applications where quantum photoelectrochemistry provides insight into fundamental processes include photoelectrochemical cells,〔Light-Induced Redox Reactions in Nanocrystalline Systems, Anders Hagfeldt and Michael Graetzel, Chem. Rev., 95, 1, 49-68 (1995)〕〔Materials interface engineering for solution-processed photovoltaics, Michael Graetzel, René A. J. Janssen, David B. Mitzi, Edward H. Sargent, Nature (insight review) 488, 304–312 (2012) doi:10.1038/nature11476

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